Tris(o-chlorobenzyl)[3-(4-methoxybenzoyl)propionato-κO]tin(IV)
نویسندگان
چکیده
The tin atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(11)H(11)O(4))], exists in a distorted tetra-hedral coordination environment. The carboxyl-ate anion is equally disordered over two positions.
منابع مشابه
Tris(2-chlorobenzyl)[3-(4-methylphenyl)prop-2-enoato-κO]tin(IV)
The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(10)H(9)O(2))], exists in a tetra-hedral geometry [Σ C-Sn-C = 341.5 (4)°]. If the doubly bonded carbonyl O atom is taken into account for the coordination sphere of Sn [Sn⋯O = 2.808 (2) Å], the coordination geometry can be described as a cis-penta-gonal bipyramid.
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The Sn atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(8)H(14)NO(2)S(2))], is coordinated by three chlorobenzyl ligands and one carboxylate O atom of the substituted acetate ligand in a distorted tetra-hedral environment. Three of the C atoms of the n-butyl group are disordered over two sites with equal occupancies.
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Tris(2-chloro-benz-yl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two mol-ecules which differ only in the position of the nitro-gen-bound H atom of the triazole ring; one mol-ecule is linked to the other mol-ecule by an N-H⋯N hydrogen bond. In the second mol-ecule, two of...
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The centrosymmetric title compound, [SnI(4)(C(21)H(21)OP)(2)], is a monomeric complex that displays a nearly octa-hedral coordination of tin(IV), with an Sn-O bond distance of 2.159 (2) Å and an average Sn-I bond distance of 2.79 (3) Å.
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The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(3)Cl(C(18)H(15)AsO)], shows a distorted C(3)ClOSn trigonal bipyramidal coordination; the axial O-Sn-Cl angle is 170.22 (4)°.
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